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Beilstein J. Org. Chem. 2014, 10, 1261–1266, doi:10.3762/bjoc.10.126
Graphical Abstract
Scheme 1: Transition metal-catalyzed allylic substitution reactions with monosubstituted allyl substrates.
Figure 1: Representative ligands developed for the regio- and enantioselective Pd-catalyzed allylic alkylatio...
Scheme 2: Preparation of 1-[bis(trifluoromethyl)phosphine]-1’-oxazolinylferrocene ligands. Reagents and condi...
Scheme 3: Comparison of the effect of ligands in the reaction.
Figure 2: Preliminary explanation of the regioselectivity.
Beilstein J. Org. Chem. 2013, 9, 1891–1896, doi:10.3762/bjoc.9.222
Scheme 1: Design of the planar chiral P,N-ligand.
Scheme 2: Synthesis of planar chiral P,N-ligand (Sp)-L1.
Scheme 3: Pd-catalyzed asymmetric allylic alkylation and amination reactions with (Sp)-L1.